Construction of WO₃/CsPbBr₃ S-scheme heterojunction via electrostatic Self-assembly for efficient and Long-Period photocatalytic CO₂ reduction

Owing to the severe photogenerated carriers recombination and low oxidation ability, the photocatalytic performance of pristine CsPbBr₃ is still unsatisfactory. Herein, melamine foam supported S-scheme WO₃/CsPbBr₃ heterojunction is successfully synthesized by electrostatic self-assembly. Because of the appropriate energy level positions, an S-scheme charge migration route between CsPbBr₃ and WO₃ is constructed. Under solar light irradiation, melamine foam assisted WO₃/CsPbBr₃ exhibits significantly enhanced photocatalytic CO₂ reduction performance under liquid H₂O medium, and the electron consumption rate (R_electron) reaches to 1225.50 μmol.g⁻¹.h⁻¹, which is 1.49- and 13.7-fold of CsPbBr₃ and WO₃, respectively, ascribing to the boosted charges transfer and the strengthened redox ability. Furthermore, S-scheme WO₃/CsPbBr₃ heterojunction also exhibits strong durability, with no noticeable reduction of product yields after four 8-h cycles.