Investigation and application of quantitative relationship between sp energy levels of Bi 3+ ion and host lattice

Lili Wang; Qiang Sun; Qingzhi Liu; Jinsheng Shi

doi:10.1016/j.jssc.2012.03.015

Investigation and application of quantitative relationship between sp energy levels of Bi ³⁺ ion and host lattice

Lili Wang
, Qiang Sun
, Qingzhi Liu
, Jinsheng Shi

Qingdao Agricultural University

Research output: Contribution to journal › Article › peer-review

119 Scopus citations

Abstract

Information on ¹S ₀- ³P ₁ (A band) and ¹S ₀- ¹P ₁ (C band) transition energy of Bi ³ ion in dozens of different compounds has been gathered and analyzed. With the use of the dielectric theory of the chemical bond for complex crystals, relationships between A and C absorption band and environmental factor h _e were established: E _A=2.9726.206exp (-h _e/0.551); E _C=3.23610.924exp (-h _e/0.644). For Bi ³ doped hosts with known structure and refractive index, it is possible to predict Bi ³ energy level position with an good accuracy of typically ±0.51 eV using the two relationships. Moreover, a direct relationship between A and C band was deduced: E _C=3.2362.290(E _A-2.972) ^0.856. Thus a very simple method to predict C band position was proposed. This work will be of great help to understand spectroscopy of Bi ³ and will be useful for developing new PDP, LED and mercury-free fluorescent lamp phosphors.

Original language	English
Pages (from-to)	142-146
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	191
DOIs	https://doi.org/10.1016/j.jssc.2012.03.015
State	Published - Jul 2012
Externally published	Yes

Keywords

A absorption band
Bi
C absorption band
Prediction

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10.1016/j.jssc.2012.03.015

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@article{09029ab65e434e2587503e2252f05b31,

title = "Investigation and application of quantitative relationship between sp energy levels of Bi 3+ ion and host lattice",

abstract = "Information on 1S 0- 3P 1 (A band) and 1S 0- 1P 1 (C band) transition energy of Bi 3 ion in dozens of different compounds has been gathered and analyzed. With the use of the dielectric theory of the chemical bond for complex crystals, relationships between A and C absorption band and environmental factor h e were established: E A=2.9726.206exp (-h e/0.551); E C=3.23610.924exp (-h e/0.644). For Bi 3 doped hosts with known structure and refractive index, it is possible to predict Bi 3 energy level position with an good accuracy of typically ±0.51 eV using the two relationships. Moreover, a direct relationship between A and C band was deduced: E C=3.2362.290(E A-2.972) 0.856. Thus a very simple method to predict C band position was proposed. This work will be of great help to understand spectroscopy of Bi 3 and will be useful for developing new PDP, LED and mercury-free fluorescent lamp phosphors.",

keywords = "A absorption band, Bi, C absorption band, Prediction",

author = "Lili Wang and Qiang Sun and Qingzhi Liu and Jinsheng Shi",

year = "2012",

month = jul,

doi = "10.1016/j.jssc.2012.03.015",

language = "英语",

volume = "191",

pages = "142--146",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

}

TY - JOUR

T1 - Investigation and application of quantitative relationship between sp energy levels of Bi 3+ ion and host lattice

AU - Wang, Lili

AU - Sun, Qiang

AU - Liu, Qingzhi

AU - Shi, Jinsheng

PY - 2012/7

Y1 - 2012/7

N2 - Information on 1S 0- 3P 1 (A band) and 1S 0- 1P 1 (C band) transition energy of Bi 3 ion in dozens of different compounds has been gathered and analyzed. With the use of the dielectric theory of the chemical bond for complex crystals, relationships between A and C absorption band and environmental factor h e were established: E A=2.9726.206exp (-h e/0.551); E C=3.23610.924exp (-h e/0.644). For Bi 3 doped hosts with known structure and refractive index, it is possible to predict Bi 3 energy level position with an good accuracy of typically ±0.51 eV using the two relationships. Moreover, a direct relationship between A and C band was deduced: E C=3.2362.290(E A-2.972) 0.856. Thus a very simple method to predict C band position was proposed. This work will be of great help to understand spectroscopy of Bi 3 and will be useful for developing new PDP, LED and mercury-free fluorescent lamp phosphors.

AB - Information on 1S 0- 3P 1 (A band) and 1S 0- 1P 1 (C band) transition energy of Bi 3 ion in dozens of different compounds has been gathered and analyzed. With the use of the dielectric theory of the chemical bond for complex crystals, relationships between A and C absorption band and environmental factor h e were established: E A=2.9726.206exp (-h e/0.551); E C=3.23610.924exp (-h e/0.644). For Bi 3 doped hosts with known structure and refractive index, it is possible to predict Bi 3 energy level position with an good accuracy of typically ±0.51 eV using the two relationships. Moreover, a direct relationship between A and C band was deduced: E C=3.2362.290(E A-2.972) 0.856. Thus a very simple method to predict C band position was proposed. This work will be of great help to understand spectroscopy of Bi 3 and will be useful for developing new PDP, LED and mercury-free fluorescent lamp phosphors.

KW - A absorption band

KW - Bi

KW - C absorption band

KW - Prediction

UR - https://www.scopus.com/pages/publications/84862200942

U2 - 10.1016/j.jssc.2012.03.015

DO - 10.1016/j.jssc.2012.03.015

M3 - 文章

AN - SCOPUS:84862200942

SN - 0022-4596

VL - 191

SP - 142

EP - 146

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -

Investigation and application of quantitative relationship between sp energy levels of Bi ³⁺ ion and host lattice

Abstract

Keywords

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